MassBank Record: EQ366407



 Danofloxacin; LC-ESI-QFT; MS2; CE: 120; R=35000; [M+H]+ 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: EQ366407
RECORD_TITLE: Danofloxacin; LC-ESI-QFT; MS2; CE: 120; R=35000; [M+H]+
DATE: 2015.08.25
AUTHORS: Stravs MDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Schymanski EDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Singer HDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Department of Environmental Chemistry, Eawag and Thomaidis N, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2015 Eawag, Duebendorf, Switzerland
COMMENT: CONFIDENCE standard compound
COMMENT: EAWAG_UCHEM_ID 3664

CH$NAME: Danofloxacin CH$NAME: 1-cyclopropyl-6-fluoro-7-(5-methyl-2-aza-5-azoniabicyclo[2.2.1]heptan-2-yl)-4-oxoquinoline-3-carboxylate CH$COMPOUND_CLASS: N/A; Environmental Standard CH$FORMULA: C19H20FN3O3 CH$EXACT_MASS: 357.14887 CH$SMILES: CN1CC2CC1CN2C3=C(C=C4C(=C3)N(C=C(C4=O)C(=O)O)C5CC5)F CH$IUPAC: InChI=1S/C19H20FN3O3/c1-21-7-12-4-11(21)8-22(12)17-6-16-13(5-15(17)20)18(24)14(19(25)26)9-23(16)10-2-3-10/h5-6,9-12H,2-4,7-8H2,1H3,(H,25,26) CH$LINK: CAS 112398-08-0 CH$LINK: PUBCHEM 14650736 CH$LINK: INCHIKEY QMLVECGLEOSESV-UHFFFAOYSA-N CH$LINK: CHEMSPIDER 10696636
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific AC$INSTRUMENT_TYPE: LC-ESI-QFT AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: IONIZATION ESI AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD AC$MASS_SPECTROMETRY: COLLISION_ENERGY 120 (nominal) AC$MASS_SPECTROMETRY: RESOLUTION 35000 AC$CHROMATOGRAPHY: COLUMN_NAME XBridge C18 3.5um, 2.1x50mm, Waters AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0 min, 50/50 at 4 min, 5/95 at 17 min, 5/95 at 25 min, 90/10 at 25.1 min, 90/10 at 30 min AC$CHROMATOGRAPHY: FLOW_RATE 200 ul/min AC$CHROMATOGRAPHY: RETENTION_TIME 4.4 min AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 164.9843 MS$FOCUSED_ION: PRECURSOR_M/Z 358.1561 MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+ MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1 MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included MS$DATA_PROCESSING: WHOLE RMassBank 1.9.6
PK$SPLASH: splash10-001i-8900000000-71f222bbf178d2374e9b PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm) 50.015 C4H2+ 1 50.0151 -1.23 51.023 C4H3+ 1 51.0229 1.05 53.0022 C3HO+ 1 53.0022 0.92 53.0386 C4H5+ 1 53.0386 0.82 53.9975 C2NO+ 1 53.9974 1.11 54.0339 C3H4N+ 1 54.0338 0.64 55.0417 C3H5N+ 1 55.0417 0.72 55.0543 C4H7+ 1 55.0542 0.61 56.0495 C3H6N+ 1 56.0495 0.97 57.0135 C3H2F+ 1 57.0135 -0.43 57.0573 C3H7N+ 1 57.0573 0.69 58.0652 C3H8N+ 1 58.0651 0.94 60.0245 C2H3FN+ 1 60.0244 2.27 63.0229 C5H3+ 2 63.0229 0.06 65.0386 C5H5+ 2 65.0386 0.51 66.0464 C5H6+ 2 66.0464 -0.18 67.0417 C4H5N+ 1 67.0417 0.44 68.0495 C4H6N+ 1 68.0495 0.36 69.0573 C4H7N+ 1 69.0573 0.57 69.0699 C5H9+ 2 69.0699 0.63 70.0651 C4H8N+ 1 70.0651 0.2 74.0964 C4H12N+ 1 74.0964 -0.08 75.0229 C6H3+ 2 75.0229 -0.22 76.0182 C5H2N+ 1 76.0182 0.98 77.0385 C6H5+ 2 77.0386 -1.12 78.0339 C5H4N+ 1 78.0338 0.57 79.0416 C5H5N+ 1 79.0417 -0.64 79.0542 C6H7+ 2 79.0542 0.3 80.0495 C5H6N+ 1 80.0495 -0.2 81.0573 C5H7N+ 1 81.0573 0.49 82.0651 C5H8N+ 1 82.0651 0.17 83.0291 C5H4F+ 1 83.0292 -0.54 83.0729 C5H9N+ 1 83.073 -0.49 84.037 C5H5F+ 1 84.037 0.6 84.0808 C5H10N+ 1 84.0808 -0.07 87.0229 C7H3+ 2 87.0229 -0.07 88.0183 C6H2N+ 1 88.0182 1.07 89.0386 C7H5+ 2 89.0386 0.04 90.0465 C7H6+ 2 90.0464 0.76 91.0543 C7H7+ 2 91.0542 1.24 93.0135 C6H2F+ 1 93.0135 -0.59 93.0573 C6H7N+ 1 93.0573 -0.11 94.0652 C6H8N+ 1 94.0651 0.47 95.0292 C6H4F+ 1 95.0292 0.58 95.0492 C6H7O+ 2 95.0491 0.41 95.0604 C5H7N2+ 1 95.0604 0.69 96.037 C6H5F+ 1 96.037 0.52 96.0444 C5H6NO+ 1 96.0444 0.1 96.0808 C6H10N+ 1 96.0808 0.56 97.0449 C6H6F+ 1 97.0448 0.98 99.0229 C8H3+ 2 99.0229 0.04 100.0182 C7H2N+ 1 100.0182 0.25 102.034 C7H4N+ 1 102.0338 1.42 102.0465 C8H6+ 2 102.0464 0.57 103.0417 C7H5N+ 1 103.0417 0.96 103.0543 C8H7+ 2 103.0542 1.1 104.0496 C7H6N+ 1 104.0495 1 105.0136 C7H2F+ 1 105.0135 0.62 105.0448 C6H5N2+ 1 105.0447 0.53 107.0292 C7H4F+ 1 107.0292 0.61 108.0245 C6H3FN+ 1 108.0244 0.71 108.037 C7H5F+ 1 108.037 0.56 108.0445 C6H6NO+ 1 108.0444 1.11 109.0323 C6H4FN+ 1 109.0322 0.75 109.0448 C7H6F+ 1 109.0448 0.14 110.0403 C6H5FN+ 1 110.0401 1.87 112.0183 C8H2N+ 1 112.0182 0.84 113.0386 C9H5+ 2 113.0386 0.47 114.034 C8H4N+ 1 114.0338 1.53 114.0465 C9H6+ 2 114.0464 1.04 115.0417 C8H5N+ 1 115.0417 0.6 115.0543 C9H7+ 2 115.0542 0.55 116.0495 C8H6N+ 1 116.0495 0.04 117.0572 C8H7N+ 1 117.0573 -1.12 118.0214 C8H3F+ 1 118.0213 0.43 118.0287 C7H4NO+ 1 118.0287 -0.34 119.0493 C8H7O+ 2 119.0491 1.17 120.0246 C7H3FN+ 1 120.0244 1.72 120.037 C8H5F+ 1 120.037 0.17 121.0323 C7H4FN+ 1 121.0322 0.34 121.0449 C8H6F+ 1 121.0448 1.12 122.0401 C7H5FN+ 1 122.0401 0.3 123.0354 C6H4FN2+ 1 123.0353 1.03 123.0478 C7H6FN+ 1 123.0479 -0.97 125.0387 C10H5+ 2 125.0386 0.83 126.0341 C9H4N+ 1 126.0338 2.26 126.0464 C10H6+ 2 126.0464 -0.17 127.0417 C9H5N+ 1 127.0417 0.78 127.0543 C10H7+ 2 127.0542 0.58 128.0495 C9H6N+ 1 128.0495 0.27 128.062 C10H8+ 2 128.0621 -0.64 129.0447 C8H5N2+ 1 129.0447 0.04 129.0574 C9H7N+ 1 129.0573 0.54 130.0653 C9H8N+ 1 130.0651 1.11 131.0291 C9H4F+ 1 131.0292 -0.19 132.0245 C8H3FN+ 1 132.0244 1.03 132.0372 C9H5F+ 1 132.037 1.67 132.0445 C8H6NO+ 1 132.0444 0.83 132.057 C9H8O+ 2 132.057 0.33 133.0323 C8H4FN+ 1 133.0322 0.23 133.0449 C9H6F+ 1 133.0448 0.56 134.0402 C8H5FN+ 1 134.0401 0.72 134.06 C8H8NO+ 1 134.06 -0.15 135.0479 C8H6FN+ 1 135.0479 0.23 136.0559 C8H7FN+ 1 136.0557 1.22 139.0292 C9H3N2+ 1 139.0291 0.61 139.0545 C11H7+ 2 139.0542 1.82 140.0495 C10H6N+ 1 140.0495 0.46 141.0447 C9H5N2+ 1 141.0447 0.18 141.0574 C10H7N+ 1 141.0573 0.35 142.0289 C9H4NO+ 1 142.0287 0.98 142.0525 C9H6N2+ 1 142.0525 -0.42 142.0651 C10H8N+ 1 142.0651 0.17 143.0605 C9H7N2+ 1 143.0604 0.74 144.0446 C9H6NO+ 1 144.0444 1.46 145.0323 C9H4FN+ 1 145.0322 0.63 145.0449 C10H6F+ 1 145.0448 0.93 145.065 C10H9O+ 2 145.0648 1.09 146.0402 C9H5FN+ 1 146.0401 1.07 146.0527 C10H7F+ 1 146.0526 0.48 146.0599 C9H8NO+ 1 146.06 -0.89 147.0354 C8H4FN2+ 1 147.0353 0.53 147.048 C9H6FN+ 1 147.0479 0.62 147.0603 C10H8F+ 1 147.0605 -0.78 148.0558 C9H7FN+ 1 148.0557 0.51 149.0512 C8H6FN2+ 1 149.051 1.79 149.0637 C9H8FN+ 1 149.0635 0.88 150.0351 C8H5FNO+ 1 150.035 1.08 150.047 C12H6+ 2 150.0464 3.99 151.0426 C8H6FNO+ 1 151.0428 -1.21 152.0498 C11H6N+ 1 152.0495 2.4 152.0623 C12H8+ 2 152.0621 1.3 153.0449 C10H5N2+ 1 153.0447 1.08 153.0574 C11H7N+ 1 153.0573 0.45 154.0401 C9H4N3+ 1 154.04 0.69 154.0652 C11H8N+ 1 154.0651 0.81 155.0604 C10H7N2+ 1 155.0604 0.23 155.0732 C11H9N+ 1 155.073 1.41 156.0679 C10H8N2+ 1 156.0682 -2.05 156.0809 C11H10N+ 1 156.0808 0.86 157.0396 C9H5N2O+ 1 157.0396 0.01 157.0452 C11H6F+ 1 157.0448 2.39 157.0523 C10H7NO+ 1 157.0522 0.54 158.0402 C10H5FN+ 1 158.0401 0.93 158.0599 C10H8NO+ 1 158.06 -0.95 159.0482 C10H6FN+ 1 159.0479 1.83 159.0553 C9H7N2O+ 1 159.0553 0.13 159.0608 C11H8F+ 1 159.0605 2.11 160.0434 C9H5FN2+ 1 160.0431 1.7 160.0557 C10H7FN+ 1 160.0557 0.29 161.0273 C9H4FNO+ 1 161.0271 1.1 161.0513 C9H6FN2+ 1 161.051 2.22 161.0637 C10H8FN+ 1 161.0635 1.25 162.0352 C9H5FNO+ 1 162.035 1.74 162.0463 C13H6+ 2 162.0464 -0.57 162.0589 C9H7FN2+ 1 162.0588 0.45 163.0424 C9H6FNO+ 2 163.0428 -2.35 163.0555 C10H8FO+ 1 163.0554 0.68 163.0665 C9H8FN2+ 1 163.0666 -0.81 164.0504 C9H7FNO+ 1 164.0506 -1.58 165.0451 C11H5N2+ 2 165.0447 2.34 165.0699 C13H9+ 2 165.0699 0.38 166.0527 C11H6N2+ 1 166.0525 0.85 166.0652 C12H8N+ 1 166.0651 0.45 167.0241 C10H3N2O+ 1 167.024 0.72 167.0605 C11H7N2+ 1 167.0604 0.87 167.073 C12H9N+ 1 167.073 0.18 168.0446 C11H6NO+ 1 168.0444 1.01 168.056 C7H7FN3O+ 2 168.0568 -4.32 168.0683 C11H8N2+ 1 168.0682 0.42 168.0805 C12H10N+ 1 168.0808 -1.88 169.0517 C11H7NO+ 1 169.0522 -2.75 169.0762 C11H9N2+ 1 169.076 0.74 170.0404 C11H5FN+ 1 170.0401 2.21 170.0529 C12H7F+ 1 170.0526 1.41 170.06 C11H8NO+ 1 170.06 -0.35 171.0482 C11H6FN+ 1 171.0479 1.82 171.0548 C10H7N2O+ 1 171.0553 -2.63 172.0558 C11H7FN+ 1 172.0557 0.44 173.0511 C10H6FN2+ 1 173.051 0.91 173.0629 C11H8FN+ 1 173.0635 -3.58 174.0351 C10H5FNO+ 1 174.035 0.53 174.0594 C10H7FN2+ 1 174.0588 3.4 174.0711 C11H9FN+ 1 174.0714 -1.46 175.0428 C10H6FNO+ 1 175.0428 -0.02 175.0668 C10H8FN2+ 1 175.0666 0.95 176.0505 C10H7FNO+ 1 176.0506 -0.9 177.0577 C13H7N+ 2 177.0573 2.54 178.0301 C9H5FNO2+ 1 178.0299 1.22 178.0425 C10H7FO2+ 1 178.0425 0.29 178.0529 C9H7FN2O+ 2 178.0537 -4.62 178.066 C10H9FNO+ 1 178.0663 -1.23 179.0378 C9H6FNO2+ 1 179.0377 0.74 179.0606 C12H7N2+ 1 179.0604 1.04 180.0446 C9H7FNO2+ 2 180.0455 -4.9 180.0556 C11H6N3+ 1 180.0556 -0.08 180.0681 C12H8N2+ 1 180.0682 -0.61 180.0805 C13H10N+ 1 180.0808 -1.64 181.0759 C12H9N2+ 1 181.076 -0.52 182.0401 C12H5FN+ 1 182.0401 0.36 182.0475 C11H6N2O+ 1 182.0475 0.25 182.0598 C12H8NO+ 1 182.06 -1.1 182.0716 C11H8N3+ 2 182.0713 1.96 183.0548 C11H7N2O+ 1 183.0553 -2.45 183.0614 C13H8F+ 1 183.0605 5 183.0681 C12H9NO+ 1 183.0679 1.12 184.0558 C12H7FN+ 1 184.0557 0.3 184.0629 C11H8N2O+ 1 184.0631 -1.16 185.0507 C11H6FN2+ 1 185.051 -1.1 185.0636 C12H8FN+ 1 185.0635 0.22 185.0713 C11H9N2O+ 2 185.0709 1.89 186.0589 C11H7FN2+ 1 186.0588 0.82 186.0714 C12H9FN+ 1 186.0714 0.25 187.0303 C10H4FN2O+ 1 187.0302 0.28 187.0432 C11H6FNO+ 1 187.0428 1.96 187.0667 C11H8FN2+ 1 187.0666 0.52 188.0144 C10H3FNO2+ 1 188.0142 0.73 188.0505 C11H7FNO+ 1 188.0506 -0.79 189.0459 C10H6FN2O+ 1 189.0459 0.38 189.0586 C11H8FNO+ 1 189.0584 0.62 189.0821 C11H10FN2+ 1 189.0823 -0.6 190.0658 C11H9FNO+ 2 190.0663 -2.41 191.0611 C10H8FN2O+ 2 191.0615 -2.39 191.0729 C14H9N+ 1 191.073 -0.27 192.0456 C10H7FNO2+ 1 192.0455 0.14 192.0683 C13H8N2+ 1 192.0682 0.31 192.0809 C14H10N+ 1 192.0808 0.86 193.0536 C10H8FNO2+ 1 193.0534 1.05 193.0761 C13H9N2+ 1 193.076 0.44 194.0608 C10H9FNO2+ 2 194.0612 -2.23 195.0194 C11H3N2O2+ 2 195.0189 2.39 195.0552 C12H7N2O+ 1 195.0553 -0.36 196.0557 C13H7FN+ 1 196.0557 0.24 197.0512 C12H6FN2+ 1 197.051 1.05 197.0709 C12H9N2O+ 1 197.0709 -0.1 198.0587 C12H7FN2+ 1 198.0588 -0.24 198.0722 C13H9FN+ 1 198.0714 4.42 199.0667 C12H8FN2+ 1 199.0666 0.54 200.0506 C12H7FNO+ 1 200.0506 0.06 200.0744 C12H9FN2+ 1 200.0744 -0.09 201.0585 C12H8FNO+ 1 201.0584 0.23 202.0544 C11H7FN2O+ 1 202.0537 3.55 202.0657 C12H9FNO+ 2 202.0663 -2.91 203.0376 C11H6FNO2+ 1 203.0377 -0.38 203.0617 C11H8FN2O+ 1 203.0615 1.14 205.0538 C11H8FNO2+ 1 205.0534 2.35 205.0767 C11H10FN2O+ 2 205.0772 -2.13 206.0248 C10H5FNO3+ 1 206.0248 -0.04 206.084 C14H10N2+ 2 206.0838 0.97 207.0553 C13H7N2O+ 1 207.0553 0.25 207.092 C14H11N2+ 2 207.0917 1.38 208.0873 C13H10N3+ 3 208.0869 1.62 210.0591 C13H7FN2+ 1 210.0588 1.34 211.0668 C13H8FN2+ 1 211.0666 0.84 212.0746 C13H9FN2+ 1 212.0744 1 212.0869 C14H11FN+ 1 212.087 -0.49 213.0824 C13H10FN2+ 1 213.0823 0.55 214.0663 C13H9FNO+ 1 214.0663 0.15 215.0252 C11H4FN2O2+ 1 215.0251 0.27 215.0617 C12H8FN2O+ 1 215.0615 1.08 217.041 C11H6FN2O2+ 1 217.0408 0.96 217.0769 C12H10FN2O+ 2 217.0772 -1.05 218.0841 C15H10N2+ 2 218.0838 1.06 221.0711 C14H9N2O+ 2 221.0709 0.95 223.0666 C14H8FN2+ 1 223.0666 -0.24 224.0739 C14H9FN2+ 1 224.0744 -2.4 226.0531 C13H7FN2O+ 2 226.0537 -2.62 227.062 C13H8FN2O+ 1 227.0615 1.99 233.0358 C11H6FN2O3+ 1 233.0357 0.57 235.0511 C11H8FN2O3+ 2 235.0513 -1.22 239.0617 C14H8FN2O+ 1 239.0615 0.89 239.0987 C15H12FN2+ 1 239.0979 3.33 255.0566 C14H8FN2O2+ 1 255.0564 0.81 PK$NUM_PEAK: 273 PK$PEAK: m/z int. rel.int. 50.015 872.2 2 51.023 2398 6 53.0022 50733.6 127 53.0386 6665.1 16 53.9975 697.8 1 54.0339 5628.7 14 55.0417 2978.4 7 55.0543 17056.5 42 56.0495 4985.5 12 57.0135 676 1 57.0573 2646.8 6 58.0652 521.9 1 60.0245 471.4 1 63.0229 1658.3 4 65.0386 18239.8 45 66.0464 2917.4 7 67.0417 143834 360 68.0495 13696.6 34 69.0573 579.7 1 69.0699 458.4 1 70.0651 29354 73 74.0964 1687.2 4 75.0229 4937.1 12 76.0182 663.2 1 77.0385 1554.2 3 78.0339 2514.7 6 79.0416 1494.1 3 79.0542 2332.1 5 80.0495 59155.3 148 81.0573 19261 48 82.0651 398758.2 999 83.0291 3373.7 8 83.0729 8176 20 84.037 1773.9 4 84.0808 10590.3 26 87.0229 662.4 1 88.0183 549.2 1 89.0386 4462.2 11 90.0465 1706.8 4 91.0543 986.5 2 93.0135 680.2 1 93.0573 1688.6 4 94.0652 17361.9 43 95.0292 673.3 1 95.0492 6607.4 16 95.0604 670.6 1 96.037 2172.8 5 96.0444 6084.2 15 96.0808 6550.5 16 97.0449 835.8 2 99.0229 2951.6 7 100.0182 488.6 1 102.034 461.2 1 102.0465 543.4 1 103.0417 550.7 1 103.0543 1806.1 4 104.0496 838.1 2 105.0136 711.1 1 105.0448 4074.1 10 107.0292 12421.8 31 108.0245 1697.8 4 108.037 3467.9 8 108.0445 966.1 2 109.0323 776.4 1 109.0448 2368.4 5 110.0403 506.4 1 112.0183 1692.9 4 113.0386 4815 12 114.034 5442.8 13 114.0465 815.7 2 115.0417 4004.7 10 115.0543 10835.8 27 116.0495 4461.1 11 117.0572 2981.3 7 118.0214 678.4 1 118.0287 1640.9 4 119.0493 2097.9 5 120.0246 2254.2 5 120.037 6123.1 15 121.0323 823.8 2 121.0449 1491.5 3 122.0401 6364.9 15 123.0354 1697.8 4 123.0478 3107.7 7 125.0387 5891.1 14 126.0341 3338.8 8 126.0464 4244 10 127.0417 2809.3 7 127.0543 5579.7 13 128.0495 7774.2 19 128.062 3224.9 8 129.0447 8251.9 20 129.0574 692 1 130.0653 1923.9 4 131.0291 506.6 1 132.0245 17166.1 43 132.0372 1852.5 4 132.0445 1959.3 4 132.057 1884.8 4 133.0323 5478.1 13 133.0449 37230.9 93 134.0402 12259.1 30 134.06 2427.5 6 135.0479 12885.3 32 136.0559 2564 6 139.0292 6365.5 15 139.0545 2327 5 140.0495 27842.6 69 141.0447 1885.2 4 141.0574 8336.7 20 142.0289 1983 4 142.0525 1997 5 142.0651 1895.4 4 143.0605 2604.6 6 144.0446 3381 8 145.0323 2555.6 6 145.0449 5603 14 145.065 2193.8 5 146.0402 9815.9 24 146.0527 19905.6 49 146.0599 3267.2 8 147.0354 2967.3 7 147.048 6813 17 147.0603 914.4 2 148.0558 11443.2 28 149.0512 2383.9 5 149.0637 500.9 1 150.0351 11099.9 27 150.047 613.5 1 151.0426 4480.3 11 152.0498 17579.1 44 152.0623 1761 4 153.0449 5269.3 13 153.0574 3002.4 7 154.0401 5562.7 13 154.0652 18172.9 45 155.0604 13433.3 33 155.0732 755.7 1 156.0679 481.3 1 156.0809 689.6 1 157.0396 6250.3 15 157.0452 2914.4 7 157.0523 2044.2 5 158.0402 9132.3 22 158.0599 3832.9 9 159.0482 15834.9 39 159.0553 2535.6 6 159.0608 1962.6 4 160.0434 3078 7 160.0557 15239.4 38 161.0273 3894.9 9 161.0513 8086.6 20 161.0637 4282.6 10 162.0352 4093.1 10 162.0463 2165.1 5 162.0589 3475.4 8 163.0424 681.2 1 163.0555 3758.8 9 163.0665 848.6 2 164.0504 7872.9 19 165.0451 2357.5 5 165.0699 6343.4 15 166.0527 5831.9 14 166.0652 3859.3 9 167.0241 3110.2 7 167.0605 12774.3 32 167.073 2001.3 5 168.0446 761.8 1 168.056 2449 6 168.0683 11481.8 28 168.0805 726.9 1 169.0517 458.2 1 169.0762 2898.8 7 170.0404 847.2 2 170.0529 1755 4 170.06 10361.9 25 171.0482 7038.6 17 171.0548 1022.1 2 172.0558 88604.5 221 173.0511 21768.9 54 173.0629 3979.6 9 174.0351 7763.9 19 174.0594 4581.8 11 174.0711 4091.7 10 175.0428 553.6 1 175.0668 2298.2 5 176.0505 1712.6 4 177.0577 574.2 1 178.0301 636 1 178.0425 1803.1 4 178.0529 1702.5 4 178.066 7442.4 18 179.0378 4868.3 12 179.0606 19099.8 47 180.0446 2278 5 180.0556 4682.9 11 180.0681 890.6 2 180.0805 742.5 1 181.0759 3581.7 8 182.0401 2081.1 5 182.0475 648.8 1 182.0598 1595.6 3 182.0716 413.4 1 183.0548 558 1 183.0614 497 1 183.0681 644.6 1 184.0558 3480.5 8 184.0629 454.2 1 185.0507 1945.8 4 185.0636 8082.1 20 185.0713 1754.6 4 186.0589 7396.3 18 186.0714 3882 9 187.0303 10542.9 26 187.0432 1773.1 4 187.0667 14142.3 35 188.0144 7329.3 18 188.0505 3923.3 9 189.0459 7215 18 189.0586 497.4 1 189.0821 490.5 1 190.0658 895.8 2 191.0611 959.9 2 191.0729 5271.7 13 192.0456 3352.3 8 192.0683 3617.3 9 192.0809 1833.5 4 193.0536 877.9 2 193.0761 5349.1 13 194.0608 599.4 1 195.0194 935.2 2 195.0552 3371.5 8 196.0557 806.5 2 197.0512 5318.4 13 197.0709 1472.8 3 198.0587 4396.6 11 198.0722 1267.1 3 199.0667 11202.7 28 200.0506 5838.3 14 200.0744 815.7 2 201.0585 2648.8 6 202.0544 795 1 202.0657 1723.8 4 203.0376 1678.9 4 203.0617 5015.5 12 205.0538 986.5 2 205.0767 2952.6 7 206.0248 1815.3 4 206.084 774.5 1 207.0553 931.8 2 207.092 528.9 1 208.0873 530.4 1 210.0591 1499.4 3 211.0668 3764.1 9 212.0746 712.9 1 212.0869 888.6 2 213.0824 865.4 2 214.0663 720.1 1 215.0252 4073.8 10 215.0617 6069.2 15 217.041 3069.5 7 217.0769 608.2 1 218.0841 849.6 2 221.0711 1594.3 3 223.0666 2015.2 5 224.0739 653.8 1 226.0531 1572.8 3 227.062 1637.9 4 233.0358 1971.6 4 235.0511 2088 5 239.0617 537 1 239.0987 501.4 1 255.0566 2654.2 6 //