MassBank Record: EQ366406



 Danofloxacin; LC-ESI-QFT; MS2; CE: 90; R=35000; [M+H]+ 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: EQ366406
RECORD_TITLE: Danofloxacin; LC-ESI-QFT; MS2; CE: 90; R=35000; [M+H]+
DATE: 2015.08.25
AUTHORS: Stravs MDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Schymanski EDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Singer HDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Department of Environmental Chemistry, Eawag and Thomaidis N, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2015 Eawag, Duebendorf, Switzerland
COMMENT: CONFIDENCE standard compound
COMMENT: EAWAG_UCHEM_ID 3664

CH$NAME: Danofloxacin CH$NAME: 1-cyclopropyl-6-fluoro-7-(5-methyl-2-aza-5-azoniabicyclo[2.2.1]heptan-2-yl)-4-oxoquinoline-3-carboxylate CH$COMPOUND_CLASS: N/A; Environmental Standard CH$FORMULA: C19H20FN3O3 CH$EXACT_MASS: 357.14887 CH$SMILES: CN1CC2CC1CN2C3=C(C=C4C(=C3)N(C=C(C4=O)C(=O)O)C5CC5)F CH$IUPAC: InChI=1S/C19H20FN3O3/c1-21-7-12-4-11(21)8-22(12)17-6-16-13(5-15(17)20)18(24)14(19(25)26)9-23(16)10-2-3-10/h5-6,9-12H,2-4,7-8H2,1H3,(H,25,26) CH$LINK: CAS 112398-08-0 CH$LINK: PUBCHEM 14650736 CH$LINK: INCHIKEY QMLVECGLEOSESV-UHFFFAOYSA-N CH$LINK: CHEMSPIDER 10696636
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific AC$INSTRUMENT_TYPE: LC-ESI-QFT AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: IONIZATION ESI AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD AC$MASS_SPECTROMETRY: COLLISION_ENERGY 90 (nominal) AC$MASS_SPECTROMETRY: RESOLUTION 35000 AC$CHROMATOGRAPHY: COLUMN_NAME XBridge C18 3.5um, 2.1x50mm, Waters AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0 min, 50/50 at 4 min, 5/95 at 17 min, 5/95 at 25 min, 90/10 at 25.1 min, 90/10 at 30 min AC$CHROMATOGRAPHY: FLOW_RATE 200 ul/min AC$CHROMATOGRAPHY: RETENTION_TIME 4.4 min AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 164.9843 MS$FOCUSED_ION: PRECURSOR_M/Z 358.1561 MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+ MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1 MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included MS$DATA_PROCESSING: WHOLE RMassBank 1.9.6
PK$SPLASH: splash10-001i-9540000000-f54438c275c5c867006a PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm) 53.0022 C3HO+ 1 53.0022 0.92 53.0386 C4H5+ 1 53.0386 0.63 54.0339 C3H4N+ 1 54.0338 0.64 55.0417 C3H5N+ 1 55.0417 0.17 55.0543 C4H7+ 1 55.0542 0.79 56.0495 C3H6N+ 1 56.0495 0.97 57.0573 C3H7N+ 1 57.0573 -0.19 58.0651 C3H8N+ 1 58.0651 -0.27 60.0245 C2H3FN+ 1 60.0244 1.1 65.0386 C5H5+ 2 65.0386 0.67 66.0464 C5H6+ 2 66.0464 0.13 67.0417 C4H5N+ 1 67.0417 0.44 67.0543 C5H7+ 2 67.0542 0.5 68.0495 C4H6N+ 1 68.0495 0.21 69.0573 C4H7N+ 1 69.0573 0.57 69.0698 C5H9+ 2 69.0699 -1.11 70.0652 C4H8N+ 1 70.0651 0.35 74.0964 C4H12N+ 1 74.0964 0.19 75.0479 C3H6FN+ 1 75.0479 0.82 79.0417 C5H5N+ 1 79.0417 -0.01 79.0543 C6H7+ 2 79.0542 0.55 80.0495 C5H6N+ 1 80.0495 0.18 81.0574 C5H7N+ 1 81.0573 0.73 82.0651 C5H8N+ 1 82.0651 0.17 83.0729 C5H9N+ 1 83.073 -0.13 84.0808 C5H10N+ 1 84.0808 0.41 93.0573 C6H7N+ 1 93.0573 0.21 94.0652 C6H8N+ 1 94.0651 0.79 95.0492 C6H7O+ 2 95.0491 0.83 95.0606 C5H7N2+ 1 95.0604 2.9 96.0445 C5H6NO+ 1 96.0444 0.73 96.0808 C6H10N+ 1 96.0808 0.25 97.0761 C5H9N2+ 1 97.076 0.36 105.0449 C6H5N2+ 1 105.0447 1.57 107.0293 C7H4F+ 1 107.0292 0.98 109.0449 C7H6F+ 1 109.0448 1.15 115.0417 C8H5N+ 1 115.0417 0.78 115.0542 C9H7+ 2 115.0542 -0.14 116.0495 C8H6N+ 1 116.0495 0.21 117.0574 C8H7N+ 1 117.0573 0.59 122.0401 C7H5FN+ 1 122.0401 0.3 126.0466 C10H6+ 2 126.0464 1.42 127.0545 C10H7+ 2 127.0542 2.39 128.0496 C9H6N+ 1 128.0495 0.97 128.0621 C10H8+ 2 128.0621 0.69 129.0449 C8H5N2+ 1 129.0447 1.28 129.0702 C10H9+ 2 129.0699 2.5 130.0653 C9H8N+ 1 130.0651 1.42 132.0243 C8H3FN+ 1 132.0244 -0.94 133.0449 C9H6F+ 1 133.0448 0.56 134.0401 C8H5FN+ 1 134.0401 0.2 134.0603 C8H8NO+ 1 134.06 1.79 135.0479 C8H6FN+ 1 135.0479 0.08 136.0559 C8H7FN+ 1 136.0557 1.37 140.0495 C10H6N+ 1 140.0495 0.03 141.0575 C10H7N+ 1 141.0573 1.34 142.0653 C10H8N+ 1 142.0651 1.23 143.0608 C9H7N2+ 1 143.0604 2.69 144.0444 C9H6NO+ 1 144.0444 0.28 145.0323 C9H4FN+ 1 145.0322 0.22 145.0648 C10H9O+ 2 145.0648 -0.22 146.0401 C9H5FN+ 1 146.0401 0.59 146.047 C8H6N2O+ 1 146.0475 -3.25 146.0527 C10H7F+ 1 146.0526 0.69 146.0593 C9H8NO+ 1 146.06 -4.93 147.048 C9H6FN+ 1 147.0479 1.1 147.0606 C10H8F+ 1 147.0605 0.99 148.0558 C9H7FN+ 1 148.0557 0.65 149.0512 C8H6FN2+ 1 149.051 1.39 150.035 C8H5FNO+ 1 150.035 0.08 151.0429 C8H6FNO+ 1 151.0428 0.51 152.0498 C11H6N+ 1 152.0495 2.33 153.0577 C11H7N+ 1 153.0573 2.41 154.0652 C11H8N+ 1 154.0651 0.61 155.0605 C10H7N2+ 1 155.0604 0.94 155.0729 C11H9N+ 1 155.073 -0.46 156.0683 C10H8N2+ 1 156.0682 0.39 156.081 C11H10N+ 1 156.0808 1.63 158.0402 C10H5FN+ 1 158.0401 0.86 158.0601 C10H8NO+ 1 158.06 0.19 159.0482 C10H6FN+ 1 159.0479 1.77 159.0607 C11H8F+ 1 159.0605 1.54 160.0437 C9H5FN2+ 1 160.0431 3.89 160.0558 C10H7FN+ 1 160.0557 0.91 161.0274 C9H4FNO+ 1 161.0271 1.78 161.0513 C9H6FN2+ 1 161.051 2.09 161.0636 C10H8FN+ 1 161.0635 0.75 162.0353 C9H5FNO+ 1 162.035 1.98 162.0591 C9H7FN2+ 1 162.0588 1.93 162.0714 C10H9FN+ 1 162.0714 0.41 163.0429 C9H6FNO+ 1 163.0428 0.41 163.0669 C9H8FN2+ 1 163.0666 1.88 164.0506 C9H7FNO+ 1 164.0506 0.01 165.0702 C13H9+ 2 165.0699 1.66 166.0529 C11H6N2+ 2 166.0525 2.29 166.0655 C12H8N+ 2 166.0651 2.37 167.0604 C11H7N2+ 1 167.0604 0.15 167.0729 C12H9N+ 1 167.073 -0.42 168.0684 C11H8N2+ 1 168.0682 0.89 168.0807 C12H10N+ 1 168.0808 -0.69 169.0761 C11H9N2+ 1 169.076 0.56 170.0602 C11H8NO+ 1 170.06 1.06 171.0478 C11H6FN+ 1 171.0479 -0.34 171.0555 C10H7N2O+ 1 171.0553 1.12 172.0558 C11H7FN+ 1 172.0557 0.62 173.0516 C10H6FN2+ 1 173.051 3.57 173.0636 C11H8FN+ 1 173.0635 0.47 174.0351 C10H5FNO+ 1 174.035 0.81 174.0591 C10H7FN2+ 1 174.0588 1.91 174.0713 C11H9FN+ 1 174.0714 -0.02 175.0429 C10H6FNO+ 1 175.0428 0.72 175.0669 C10H8FN2+ 1 175.0666 1.7 176.0507 C10H7FNO+ 1 176.0506 0.58 176.0746 C10H9FN2+ 1 176.0744 0.98 177.0821 C10H10FN2+ 1 177.0823 -0.69 178.0427 C10H7FO2+ 1 178.0425 1.3 178.0542 C9H7FN2O+ 1 178.0537 2.63 178.0663 C10H9FNO+ 1 178.0663 0.23 179.0378 C9H6FNO2+ 1 179.0377 0.4 179.0606 C12H7N2+ 1 179.0604 1.15 180.0448 C9H7FNO2+ 2 180.0455 -3.91 180.0684 C12H8N2+ 1 180.0682 0.83 180.081 C13H10N+ 1 180.0808 1.13 181.0761 C12H9N2+ 1 181.076 0.58 182.0398 C12H5FN+ 1 182.0401 -1.23 182.0597 C12H8NO+ 1 182.06 -1.7 182.0843 C12H10N2+ 2 182.0838 2.31 183.055 C11H7N2O+ 1 183.0553 -1.74 183.068 C12H9NO+ 1 183.0679 0.74 183.0919 C12H11N2+ 2 183.0917 1.39 184.0558 C12H7FN+ 1 184.0557 0.52 184.0634 C11H8N2O+ 2 184.0631 1.55 184.0756 C12H10NO+ 1 184.0757 -0.44 185.051 C11H6FN2+ 1 185.051 0.25 185.0637 C12H8FN+ 1 185.0635 0.82 185.0714 C11H9N2O+ 2 185.0709 2.33 186.059 C11H7FN2+ 1 186.0588 1.03 186.0715 C12H9FN+ 1 186.0714 0.73 187.0303 C10H4FN2O+ 1 187.0302 0.6 187.043 C11H6FNO+ 1 187.0428 1.32 187.0668 C11H8FN2+ 1 187.0666 0.95 188.0143 C10H3FNO2+ 1 188.0142 0.57 188.038 C10H5FN2O+ 1 188.038 -0.01 188.051 C11H7FNO+ 1 188.0506 2.24 188.0744 C11H9FN2+ 1 188.0744 0.06 189.046 C10H6FN2O+ 1 189.0459 0.54 189.0824 C11H10FN2+ 1 189.0823 0.67 190.0539 C10H7FN2O+ 1 190.0537 1.09 190.0665 C11H9FNO+ 1 190.0663 1.17 191.0619 C10H8FN2O+ 1 191.0615 1.9 191.0731 C14H9N+ 1 191.073 0.57 192.0457 C10H7FNO2+ 1 192.0455 0.92 192.0686 C13H8N2+ 2 192.0682 2.29 192.0804 C14H10N+ 1 192.0808 -1.9 193.0538 C10H8FNO2+ 1 193.0534 2.44 193.0763 C13H9N2+ 2 193.076 1.32 194.0838 C13H10N2+ 1 194.0838 -0.15 195.0192 C11H3N2O2+ 2 195.0189 1.52 195.0318 C9H6FNO3+ 2 195.0326 -4.27 195.0554 C12H7N2O+ 1 195.0553 0.77 195.092 C13H11N2+ 2 195.0917 1.87 196.0628 C12H8N2O+ 1 196.0631 -1.71 197.0508 C12H6FN2+ 1 197.051 -0.72 197.0706 C12H9N2O+ 1 197.0709 -1.87 197.1077 C13H13N2+ 2 197.1073 2 198.0587 C12H7FN2+ 1 198.0588 -0.24 198.0716 C13H9FN+ 1 198.0714 1.04 199.0667 C12H8FN2+ 1 199.0666 0.54 200.0507 C12H7FNO+ 1 200.0506 0.21 200.0746 C12H9FN2+ 1 200.0744 1.01 201.0586 C12H8FNO+ 1 201.0584 0.63 201.0823 C12H10FN2+ 1 201.0823 0.08 202.0301 C11H5FNO2+ 1 202.0299 1.22 202.0541 C11H7FN2O+ 1 202.0537 1.82 202.0664 C12H9FNO+ 1 202.0663 0.8 202.0903 C12H11FN2+ 1 202.0901 1.15 203.0617 C11H8FN2O+ 1 203.0615 0.75 204.033 C10H5FN2O2+ 1 204.033 0.01 205.0536 C11H8FNO2+ 1 205.0534 1.23 205.0765 C11H10FN2O+ 2 205.0772 -3.4 206.025 C10H5FNO3+ 1 206.0248 0.98 206.0839 C14H10N2+ 1 206.0838 0.24 207.0559 C13H7N2O+ 2 207.0553 3.05 207.0917 C14H11N2+ 1 207.0917 0.22 208.0862 C13H10N3+ 1 208.0869 -3.33 211.0668 C13H8FN2+ 1 211.0666 1.12 212.0749 C13H9FN2+ 1 212.0744 2.04 212.0871 C14H11FN+ 1 212.087 0.59 213.0462 C12H6FN2O+ 1 213.0459 1.51 213.0824 C13H10FN2+ 1 213.0823 0.69 214.0546 C12H7FN2O+ 1 214.0537 4.01 214.0666 C13H9FNO+ 1 214.0663 1.74 214.0904 C13H11FN2+ 1 214.0901 1.41 215.0253 C11H4FN2O2+ 1 215.0251 0.87 215.0618 C12H8FN2O+ 1 215.0615 1.22 216.0696 C12H9FN2O+ 1 216.0693 1.42 217.041 C11H6FN2O2+ 1 217.0408 1.14 217.0772 C12H10FN2O+ 1 217.0772 0.29 218.0488 C11H7FN2O2+ 1 218.0486 0.84 218.0838 C15H10N2+ 1 218.0838 -0.41 219.0919 C12H12FN2O+ 2 219.0928 -4.05 220.0408 C11H7FNO3+ 1 220.0404 1.37 221.0482 C11H8FNO3+ 1 221.0483 -0.1 221.071 C14H9N2O+ 2 221.0709 0.41 221.1075 C15H13N2+ 2 221.1073 0.97 222.0441 C10H7FN2O3+ 1 222.0435 2.56 222.0709 C15H9FN+ 1 222.0714 -2.13 223.0506 C13H7N2O2+ 2 223.0502 1.73 223.0666 C14H8FN2+ 1 223.0666 0.03 223.0868 C14H11N2O+ 2 223.0866 0.85 224.0749 C14H9FN2+ 1 224.0744 1.93 225.0823 C14H10FN2+ 1 225.0823 0.16 226.0533 C13H7FN2O+ 2 226.0537 -1.74 227.0617 C13H8FN2O+ 1 227.0615 0.85 227.0979 C14H12FN2+ 1 227.0979 -0.06 228.0533 C12H8N2O3+ 1 228.0529 1.74 228.0692 C13H9FN2O+ 2 228.0693 -0.8 229.0772 C13H10FN2O+ 1 229.0772 0.36 230.085 C13H11FN2O+ 1 230.085 0.16 231.0927 C13H12FN2O+ 2 231.0928 -0.55 233.036 C11H6FN2O3+ 1 233.0357 1.34 233.0481 C12H8FNO3+ 2 233.0483 -0.91 234.0562 C12H9FNO3+ 1 234.0561 0.31 235.0516 C11H8FN2O3+ 1 235.0513 1.25 235.0867 C15H11N2O+ 2 235.0866 0.56 236.0593 C11H9FN2O3+ 1 236.0592 0.42 236.0825 C11H11FN3O2+ 3 236.083 -1.87 237.1025 C15H13N2O+ 2 237.1022 1.18 238.0976 C14H12N3O+ 2 238.0975 0.47 239.0615 C14H8FN2O+ 2 239.0615 0.09 239.0982 C15H12FN2+ 1 239.0979 1.16 240.0701 C14H9FN2O+ 1 240.0693 3.11 241.0771 C14H10FN2O+ 2 241.0772 -0.49 243.0566 C13H8FN2O2+ 1 243.0564 0.73 244.0644 C13H9FN2O2+ 1 244.0643 0.46 247.0519 C12H8FN2O3+ 1 247.0513 2.36 253.0773 C15H10FN2O+ 2 253.0772 0.37 254.049 C14H7FN2O2+ 1 254.0486 1.39 255.0566 C14H8FN2O2+ 1 255.0564 0.7 256.0646 C14H9FN2O2+ 1 256.0643 1.46 259.0514 C13H8FN2O3+ 2 259.0513 0.21 273.0672 C14H10FN2O3+ 2 273.067 0.56 275.0824 C14H12FN2O3+ 2 275.0826 -0.93 278.0928 C16H12N3O2+ 3 278.0924 1.43 298.0983 C16H13FN3O2+ 2 298.0986 -1.18 PK$NUM_PEAK: 245 PK$PEAK: m/z int. rel.int. 53.0022 12590.2 18 53.0386 4134.8 6 54.0339 2976.1 4 55.0417 1845.8 2 55.0543 12942.5 19 56.0495 4068.1 6 57.0573 2618.9 3 58.0651 1736 2 60.0245 730.3 1 65.0386 13039.8 19 66.0464 2050.6 3 67.0417 79358.8 119 67.0543 8816.8 13 68.0495 24338.2 36 69.0573 740.9 1 69.0698 1888 2 70.0652 68519.7 103 74.0964 900 1 75.0479 711.9 1 79.0417 1038.3 1 79.0543 7240.8 10 80.0495 44603.5 67 81.0574 34363.4 51 82.0651 664316.2 999 83.0729 52259.1 78 84.0808 22677 34 93.0573 681.6 1 94.0652 40823.6 61 95.0492 3898.6 5 95.0606 691.5 1 96.0445 4835.1 7 96.0808 27141 40 97.0761 5415 8 105.0449 2387 3 107.0293 945.3 1 109.0449 1621.4 2 115.0417 915.3 1 115.0542 3713.3 5 116.0495 3023.9 4 117.0574 2292.8 3 122.0401 2788.8 4 126.0466 806.1 1 127.0545 3500.3 5 128.0496 3808 5 128.0621 2174.5 3 129.0449 2093.2 3 129.0702 741.9 1 130.0653 1588.4 2 132.0243 1805.7 2 133.0449 10493 15 134.0401 2423.5 3 134.0603 940.3 1 135.0479 8326.3 12 136.0559 6148.2 9 140.0495 5530.8 8 141.0575 3653.6 5 142.0653 1035.8 1 143.0608 756.4 1 144.0444 1924.7 2 145.0323 679.5 1 145.0648 3394.8 5 146.0401 5564.2 8 146.047 789.9 1 146.0527 11650.3 17 146.0593 935.5 1 147.048 2097.3 3 147.0606 3971.3 5 148.0558 11030.1 16 149.0512 4784.7 7 150.035 3146.9 4 151.0429 3565.4 5 152.0498 4626.8 6 153.0577 919.3 1 154.0652 18487.3 27 155.0605 8901.7 13 155.0729 3238.2 4 156.0683 2176 3 156.081 1039 1 158.0402 2351.1 3 158.0601 1021.9 1 159.0482 6546.6 9 159.0607 938.1 1 160.0437 3648.4 5 160.0558 17002.7 25 161.0274 2252.3 3 161.0513 7549.8 11 161.0636 6262.2 9 162.0353 4390.3 6 162.0591 8176.9 12 162.0714 2441.6 3 163.0429 2192.3 3 163.0669 2360 3 164.0506 6967.5 10 165.0702 3300.5 4 166.0529 795.2 1 166.0655 2012 3 167.0604 10586.1 15 167.0729 2113.3 3 168.0684 16211.3 24 168.0807 1838.3 2 169.0761 4094 6 170.0602 4093.7 6 171.0478 1899.1 2 171.0555 1838.4 2 172.0558 64009 96 173.0516 9102.1 13 173.0636 14612.3 21 174.0351 6480.6 9 174.0591 6300 9 174.0713 10565.5 15 175.0429 1646.5 2 175.0669 5318.3 7 176.0507 2443.1 3 176.0746 857.5 1 177.0821 800.4 1 178.0427 3365.3 5 178.0542 6782 10 178.0663 17874.1 26 179.0378 4180.7 6 179.0606 14972.9 22 180.0448 3452.3 5 180.0684 2229.5 3 180.081 2215.4 3 181.0761 5145.6 7 182.0398 991.4 1 182.0597 2950.3 4 182.0843 1995 3 183.055 762.9 1 183.068 779.8 1 183.0919 991.4 1 184.0558 2540.3 3 184.0634 2741.9 4 184.0756 1489 2 185.051 941.6 1 185.0637 7094.1 10 185.0714 2486 3 186.059 9205 13 186.0715 5330.2 8 187.0303 12876.7 19 187.043 4765.7 7 187.0668 57818.8 86 188.0143 12107.9 18 188.038 765 1 188.051 3828.3 5 188.0744 2757.7 4 189.046 9220 13 189.0824 2552.7 3 190.0539 2703.2 4 190.0665 808.7 1 191.0619 3745.3 5 191.0731 2740.3 4 192.0457 1871.9 2 192.0686 2493.3 3 192.0804 3037.5 4 193.0538 1793.3 2 193.0763 7444.3 11 194.0838 2165.9 3 195.0192 2290.3 3 195.0318 772.2 1 195.0554 3488.2 5 195.092 1847.1 2 196.0628 2919.2 4 197.0508 2327.3 3 197.0706 3444.9 5 197.1077 808.9 1 198.0587 4408.6 6 198.0716 3699.9 5 199.0667 26324.9 39 200.0507 11624.2 17 200.0746 7503.7 11 201.0586 11667.8 17 201.0823 5586.5 8 202.0301 1676.9 2 202.0541 2528.7 3 202.0664 17499.4 26 202.0903 4750 7 203.0617 25343.2 38 204.033 2035.1 3 205.0536 4624.9 6 205.0765 2771.7 4 206.025 1015.4 1 206.0839 2558.2 3 207.0559 2648.3 3 207.0917 1884.6 2 208.0862 1484.9 2 211.0668 7052.7 10 212.0749 4852.7 7 212.0871 11809.4 17 213.0462 1036.3 1 213.0824 9991.7 15 214.0546 766.9 1 214.0666 3160.7 4 214.0904 4826.8 7 215.0253 39577.2 59 215.0618 38460.1 57 216.0696 2993.7 4 217.041 16622.4 24 217.0772 3537.9 5 218.0488 8887.1 13 218.0838 697.5 1 219.0919 4431.1 6 220.0408 2641.5 3 221.0482 861.6 1 221.071 4140.4 6 221.1075 848.2 1 222.0441 692.5 1 222.0709 743.9 1 223.0506 861.2 1 223.0666 968.4 1 223.0868 1713.4 2 224.0749 2889.7 4 225.0823 3117.1 4 226.0533 4268.5 6 227.0617 16765.1 25 227.0979 3087.5 4 228.0533 1991.5 2 228.0692 1712.6 2 229.0772 6892.6 10 230.085 1008.3 1 231.0927 3438.2 5 233.036 17380.4 26 233.0481 1830.5 2 234.0562 723.3 1 235.0516 8873.9 13 235.0867 1655.8 2 236.0593 2878.1 4 236.0825 932.8 1 237.1025 2359.5 3 238.0976 2490.6 3 239.0615 2003.2 3 239.0982 7641 11 240.0701 1607.2 2 241.0771 6175.1 9 243.0566 2008.2 3 244.0644 861.2 1 247.0519 3627.3 5 253.0773 2852.5 4 254.049 999.9 1 255.0566 102072.7 153 256.0646 978.1 1 259.0514 905.3 1 273.0672 29678.6 44 275.0824 748.5 1 278.0928 1846.9 2 298.0983 701 1 //