MassBank Record: EQ366405



 Danofloxacin; LC-ESI-QFT; MS2; CE: 75; R=35000; [M+H]+ 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: EQ366405
RECORD_TITLE: Danofloxacin; LC-ESI-QFT; MS2; CE: 75; R=35000; [M+H]+
DATE: 2015.08.25
AUTHORS: Stravs MDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Schymanski EDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Singer HDepartment of Environmental Chemistry, Eawag and Thomaidis N, University of Athens, Department of Environmental Chemistry, Eawag and Thomaidis N, University of Athens
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2015 Eawag, Duebendorf, Switzerland
COMMENT: CONFIDENCE standard compound
COMMENT: EAWAG_UCHEM_ID 3664

CH$NAME: Danofloxacin CH$NAME: 1-cyclopropyl-6-fluoro-7-(5-methyl-2-aza-5-azoniabicyclo[2.2.1]heptan-2-yl)-4-oxoquinoline-3-carboxylate CH$COMPOUND_CLASS: N/A; Environmental Standard CH$FORMULA: C19H20FN3O3 CH$EXACT_MASS: 357.14887 CH$SMILES: CN1CC2CC1CN2C3=C(C=C4C(=C3)N(C=C(C4=O)C(=O)O)C5CC5)F CH$IUPAC: InChI=1S/C19H20FN3O3/c1-21-7-12-4-11(21)8-22(12)17-6-16-13(5-15(17)20)18(24)14(19(25)26)9-23(16)10-2-3-10/h5-6,9-12H,2-4,7-8H2,1H3,(H,25,26) CH$LINK: CAS 112398-08-0 CH$LINK: PUBCHEM 14650736 CH$LINK: INCHIKEY QMLVECGLEOSESV-UHFFFAOYSA-N CH$LINK: CHEMSPIDER 10696636
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific AC$INSTRUMENT_TYPE: LC-ESI-QFT AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: IONIZATION ESI AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD AC$MASS_SPECTROMETRY: COLLISION_ENERGY 75 (nominal) AC$MASS_SPECTROMETRY: RESOLUTION 35000 AC$CHROMATOGRAPHY: COLUMN_NAME XBridge C18 3.5um, 2.1x50mm, Waters AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0 min, 50/50 at 4 min, 5/95 at 17 min, 5/95 at 25 min, 90/10 at 25.1 min, 90/10 at 30 min AC$CHROMATOGRAPHY: FLOW_RATE 200 ul/min AC$CHROMATOGRAPHY: RETENTION_TIME 4.4 min AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 164.9843 MS$FOCUSED_ION: PRECURSOR_M/Z 358.1561 MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+ MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1 MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included MS$DATA_PROCESSING: WHOLE RMassBank 1.9.6
PK$SPLASH: splash10-001i-9260000000-043723b51191d1927511 PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm) 53.0022 C3HO+ 1 53.0022 -0.21 53.0387 C4H5+ 1 53.0386 1.76 54.0338 C3H4N+ 1 54.0338 0.27 55.0416 C3H5N+ 1 55.0417 -0.19 55.0542 C4H7+ 1 55.0542 0.06 56.0495 C3H6N+ 1 56.0495 0.61 57.0573 C3H7N+ 1 57.0573 -0.01 58.0651 C3H8N+ 1 58.0651 0.07 60.0245 C2H3FN+ 1 60.0244 0.94 65.0386 C5H5+ 2 65.0386 0.36 66.0464 C5H6+ 2 66.0464 0.28 67.0417 C4H5N+ 1 67.0417 0.29 67.0542 C5H7+ 2 67.0542 0.2 68.0495 C4H6N+ 1 68.0495 0.21 69.0699 C5H9+ 2 69.0699 -0.1 70.0651 C4H8N+ 1 70.0651 0.2 75.0479 C3H6FN+ 1 75.0479 0.02 79.0543 C6H7+ 2 79.0542 0.42 80.0495 C5H6N+ 1 80.0495 0.18 81.0573 C5H7N+ 1 81.0573 0.61 82.0651 C5H8N+ 1 82.0651 0.17 83.0729 C5H9N+ 1 83.073 -0.25 84.0808 C5H10N+ 1 84.0808 0.17 94.0652 C6H8N+ 1 94.0651 0.58 95.0492 C6H7O+ 2 95.0491 0.72 96.0808 C6H10N+ 1 96.0808 0.25 97.076 C5H9N2+ 1 97.076 -0.05 97.0887 C6H11N+ 1 97.0886 1.02 105.0449 C6H5N2+ 1 105.0447 1.29 115.0543 C9H7+ 2 115.0542 0.29 128.0498 C9H6N+ 1 128.0495 2.53 128.0622 C10H8+ 2 128.0621 0.85 129.07 C10H9+ 2 129.0699 0.65 133.0449 C9H6F+ 1 133.0448 0.41 135.0481 C8H6FN+ 1 135.0479 1.42 136.0559 C8H7FN+ 1 136.0557 1.37 141.0573 C10H7N+ 1 141.0573 0.14 142.0654 C10H8N+ 1 142.0651 2 145.0651 C10H9O+ 2 145.0648 2.13 146.0528 C10H7F+ 1 146.0526 1.3 146.06 C9H8NO+ 1 146.06 -0.28 147.048 C9H6FN+ 1 147.0479 0.62 147.0605 C10H8F+ 1 147.0605 -0.03 148.0557 C9H7FN+ 1 148.0557 0.11 149.0512 C8H6FN2+ 1 149.051 1.52 151.0431 C8H6FNO+ 1 151.0428 2.03 154.0652 C11H8N+ 1 154.0651 0.48 155.0603 C10H7N2+ 1 155.0604 -0.55 155.0731 C11H9N+ 1 155.073 1.29 156.0683 C10H8N2+ 1 156.0682 0.58 156.0813 C11H10N+ 2 156.0808 3.49 158.0602 C10H8NO+ 1 158.06 1.14 159.0482 C10H6FN+ 1 159.0479 1.77 160.0434 C9H5FN2+ 1 160.0431 1.83 160.0557 C10H7FN+ 1 160.0557 0.29 161.0511 C9H6FN2+ 1 161.051 0.67 161.0635 C10H8FN+ 1 161.0635 -0.06 162.0352 C9H5FNO+ 1 162.035 1.43 162.0588 C9H7FN2+ 1 162.0588 0.07 162.0716 C10H9FN+ 1 162.0714 1.58 163.0668 C9H8FN2+ 1 163.0666 0.96 164.0506 C9H7FNO+ 1 164.0506 0.19 166.0658 C12H8N+ 2 166.0651 3.82 167.0607 C11H7N2+ 1 167.0604 1.77 167.0731 C12H9N+ 1 167.073 1.01 168.0683 C11H8N2+ 1 168.0682 0.72 168.0808 C12H10N+ 1 168.0808 0.26 169.0523 C11H7NO+ 1 169.0522 0.8 169.0761 C11H9N2+ 1 169.076 0.45 172.0558 C11H7FN+ 1 172.0557 0.62 173.0512 C10H6FN2+ 1 173.051 1.2 173.0637 C11H8FN+ 1 173.0635 1.05 174.0351 C10H5FNO+ 1 174.035 0.53 174.0594 C10H7FN2+ 1 174.0588 3.86 174.0714 C11H9FN+ 1 174.0714 0.32 175.0669 C10H8FN2+ 1 175.0666 1.75 176.0508 C10H7FNO+ 1 176.0506 1.2 176.0745 C10H9FN2+ 1 176.0744 0.41 178.0428 C10H7FO2+ 1 178.0425 1.97 178.0539 C9H7FN2O+ 1 178.0537 1.17 178.0661 C10H9FNO+ 1 178.0663 -0.95 179.0381 C9H6FNO2+ 1 179.0377 2.02 179.061 C9H8FN2O+ 2 179.0615 -2.95 180.0809 C13H10N+ 1 180.0808 0.52 181.076 C12H9N2+ 1 181.076 -0.41 182.0605 C12H8NO+ 2 182.06 2.42 182.084 C12H10N2+ 1 182.0838 0.72 183.0916 C12H11N2+ 1 183.0917 -0.24 184.0394 C11H6NO2+ 1 184.0393 0.68 184.0563 C12H7FN+ 1 184.0557 3.08 184.0629 C11H8N2O+ 1 184.0631 -1 185.0639 C12H8FN+ 1 185.0635 1.79 185.071 C11H9N2O+ 1 185.0709 0.17 186.059 C11H7FN2+ 1 186.0588 1.03 186.0714 C12H9FN+ 1 186.0714 0.41 187.0302 C10H4FN2O+ 1 187.0302 0.12 187.0433 C11H6FNO+ 1 187.0428 2.55 187.0668 C11H8FN2+ 1 187.0666 0.89 188.0145 C10H3FNO2+ 1 188.0142 1.63 188.0508 C11H7FNO+ 1 188.0506 0.75 188.0747 C11H9FN2+ 1 188.0744 1.55 188.0874 C12H11FN+ 1 188.087 2.16 189.046 C10H6FN2O+ 1 189.0459 0.49 189.0823 C11H10FN2+ 1 189.0823 0.46 189.0951 C12H12FN+ 1 189.0948 1.54 190.0539 C10H7FN2O+ 1 190.0537 0.83 191.0617 C10H8FN2O+ 1 191.0615 1.11 192.0691 C13H8N2+ 2 192.0682 4.43 192.0809 C14H10N+ 1 192.0808 0.7 193.0762 C13H9N2+ 1 193.076 0.91 193.089 C14H11N+ 2 193.0886 1.91 194.0838 C13H10N2+ 1 194.0838 -0.1 195.0328 C9H6FNO3+ 1 195.0326 0.86 195.0553 C12H7N2O+ 1 195.0553 0 195.0918 C13H11N2+ 1 195.0917 0.49 196.0634 C12H8N2O+ 2 196.0631 1.66 197.0477 C12H7NO2+ 2 197.0471 2.64 197.0708 C12H9N2O+ 1 197.0709 -0.66 197.1075 C13H13N2+ 2 197.1073 1.09 198.0716 C13H9FN+ 1 198.0714 1.19 199.0668 C12H8FN2+ 1 199.0666 0.94 200.0507 C12H7FNO+ 1 200.0506 0.66 200.0745 C12H9FN2+ 1 200.0744 0.26 201.0585 C12H8FNO+ 1 201.0584 0.53 201.0823 C12H10FN2+ 1 201.0823 0.08 202.0303 C11H5FNO2+ 1 202.0299 2.06 202.054 C11H7FN2O+ 1 202.0537 1.42 202.0664 C12H9FNO+ 1 202.0663 0.5 202.09 C12H11FN2+ 1 202.0901 -0.14 203.0616 C11H8FN2O+ 1 203.0615 0.55 203.098 C12H12FN2+ 1 203.0979 0.48 205.0538 C11H8FNO2+ 1 205.0534 2.11 205.0772 C11H10FN2O+ 1 205.0772 0.3 206.0844 C14H10N2+ 2 206.0838 2.62 207.0922 C14H11N2+ 2 207.0917 2.34 209.0712 C13H9N2O+ 2 209.0709 1.25 209.1075 C14H13N2+ 2 209.1073 0.84 211.0662 C13H8FN2+ 1 211.0666 -1.96 211.0876 C13H11N2O+ 2 211.0866 4.6 212.0748 C13H9FN2+ 1 212.0744 1.66 212.0873 C14H11FN+ 1 212.087 1.49 213.0457 C12H6FN2O+ 2 213.0459 -0.79 213.0826 C13H10FN2+ 1 213.0823 1.53 213.0947 C14H12FN+ 1 213.0948 -0.42 214.0666 C13H9FNO+ 1 214.0663 1.6 214.0904 C13H11FN2+ 1 214.0901 1.36 215.0253 C11H4FN2O2+ 1 215.0251 0.69 215.0618 C12H8FN2O+ 1 215.0615 1.27 215.0976 C13H12FN2+ 1 215.0979 -1.27 216.0697 C12H9FN2O+ 1 216.0693 1.79 216.0823 C13H11FNO+ 1 216.0819 1.86 217.0409 C11H6FN2O2+ 1 217.0408 0.73 217.0774 C12H10FN2O+ 1 217.0772 1.02 218.0488 C11H7FN2O2+ 1 218.0486 1.11 219.0924 C12H12FN2O+ 2 219.0928 -1.77 220.0408 C11H7FNO3+ 1 220.0404 1.37 221.0484 C11H8FNO3+ 1 221.0483 0.53 221.0713 C14H9N2O+ 2 221.0709 1.63 221.1077 C15H13N2+ 2 221.1073 1.61 222.0435 C10H7FN2O3+ 1 222.0435 -0.14 222.0798 C14H10N2O+ 2 222.0788 4.75 223.0504 C13H7N2O2+ 2 223.0502 0.66 223.0865 C14H11N2O+ 1 223.0866 -0.27 224.0748 C14H9FN2+ 1 224.0744 1.84 225.0824 C14H10FN2+ 1 225.0823 0.83 226.0535 C13H7FN2O+ 2 226.0537 -0.98 226.0904 C14H11FN2+ 1 226.0901 1.56 227.0617 C13H8FN2O+ 1 227.0615 0.85 227.098 C14H12FN2+ 1 227.0979 0.29 228.0539 C12H8N2O3+ 1 228.0529 4.06 228.0695 C13H9FN2O+ 1 228.0693 0.69 228.0822 C14H11FNO+ 1 228.0819 1.01 229.0411 C12H6FN2O2+ 1 229.0408 1.48 229.0773 C13H10FN2O+ 1 229.0772 0.58 230.0485 C12H7FN2O2+ 2 230.0486 -0.42 230.0853 C13H11FN2O+ 1 230.085 1.42 231.0563 C12H8FN2O2+ 2 231.0564 -0.57 231.0931 C13H12FN2O+ 1 231.0928 1.01 233.036 C11H6FN2O3+ 1 233.0357 1.34 233.048 C12H8FNO3+ 2 233.0483 -0.96 234.0565 C12H9FNO3+ 1 234.0561 1.55 235.0514 C11H8FN2O3+ 1 235.0513 0.23 235.0641 C12H10FNO3+ 1 235.0639 0.58 235.087 C15H11N2O+ 2 235.0866 1.79 236.0592 C11H9FN2O3+ 1 236.0592 0.29 237.1022 C15H13N2O+ 2 237.1022 -0.04 238.098 C14H12N3O+ 3 238.0975 2.19 239.0615 C14H8FN2O+ 2 239.0615 0.09 239.0979 C15H12FN2+ 1 239.0979 0.15 240.07 C14H9FN2O+ 1 240.0693 2.86 240.0815 C15H11FNO+ 2 240.0819 -1.87 240.1059 C15H13FN2+ 1 240.1057 0.84 241.0772 C14H10FN2O+ 1 241.0772 0.3 241.1141 C15H14FN2+ 1 241.1136 2.1 242.0855 C14H11FN2O+ 1 242.085 2.22 243.0564 C13H8FN2O2+ 2 243.0564 -0.09 243.0928 C14H12FN2O+ 2 243.0928 0.09 245.0726 C13H10FN2O2+ 1 245.0721 2.28 245.1089 C14H14FN2O+ 1 245.1085 1.76 246.0566 C13H9FNO3+ 1 246.0561 1.96 247.052 C12H8FN2O3+ 1 247.0513 2.48 248.1185 C16H14N3+ 3 248.1182 1.23 252.1131 C15H14N3O+ 2 252.1131 -0.11 253.0774 C15H10FN2O+ 1 253.0772 0.8 254.0483 C14H7FN2O2+ 2 254.0486 -1.01 255.0566 C14H8FN2O2+ 1 255.0564 0.54 256.0644 C14H9FN2O2+ 2 256.0643 0.52 257.0724 C14H10FN2O2+ 1 257.0721 1.2 257.1087 C15H14FN2O+ 1 257.1085 0.79 261.0674 C13H10FN2O3+ 1 261.067 1.66 263.0832 C13H12FN2O3+ 1 263.0826 2.14 264.0769 C15H10N3O2+ 3 264.0768 0.67 267.0925 C16H12FN2O+ 2 267.0928 -1.08 268.1001 C16H13FN2O+ 2 268.1006 -2.02 269.0722 C15H10FN2O2+ 2 269.0721 0.59 269.1081 C16H14FN2O+ 2 269.1085 -1.25 271.1243 C16H16FN2O+ 2 271.1241 0.71 273.0672 C14H10FN2O3+ 2 273.067 0.56 274.0751 C14H11FN2O3+ 1 274.0748 1.09 275.0828 C14H12FN2O3+ 2 275.0826 0.7 277.0989 C14H14FN2O3+ 1 277.0983 2.18 278.0924 C16H12N3O2+ 3 278.0924 0.1 279.1007 C16H13N3O2+ 3 279.1002 1.62 281.1091 C17H14FN2O+ 1 281.1085 2.36 282.0883 C15H12N3O3+ 1 282.0873 3.55 283.1244 C17H16FN2O+ 1 283.1241 0.89 284.0827 C15H11FN3O2+ 2 284.083 -0.85 287.0832 C15H12FN2O3+ 1 287.0826 1.86 289.0983 C15H14FN2O3+ 2 289.0983 -0.02 298.0986 C16H13FN3O2+ 3 298.0986 0.03 301.0985 C16H14FN2O3+ 2 301.0983 0.57 315.1143 C17H16FN2O3+ 1 315.1139 1.02 340.1465 C19H19FN3O2+ 1 340.1456 2.58 358.1564 C19H21FN3O3+ 1 358.1561 0.74 PK$NUM_PEAK: 234 PK$PEAK: m/z int. rel.int. 53.0022 4791.7 5 53.0387 3144 3 54.0338 1755.5 2 55.0416 1094.4 1 55.0542 7582.2 9 56.0495 4253 5 57.0573 4927.9 6 58.0651 1964 2 60.0245 1809.9 2 65.0386 8697.1 10 66.0464 1792.5 2 67.0417 45351 55 67.0542 11054.9 13 68.0495 33191 40 69.0699 2644.1 3 70.0651 84642.6 103 75.0479 4317.9 5 79.0543 12631.1 15 80.0495 32185.5 39 81.0573 41976 51 82.0651 818498.9 999 83.0729 107326.6 130 84.0808 25880.9 31 94.0652 59211.1 72 95.0492 2866.8 3 96.0808 58711.1 71 97.076 7223.4 8 97.0887 1855.2 2 105.0449 2082.5 2 115.0543 857.4 1 128.0498 1691.2 2 128.0622 1058.5 1 129.07 2023.5 2 133.0449 2332.6 2 135.0481 3610 4 136.0559 2494.2 3 141.0573 2226.9 2 142.0654 1636 1 145.0651 1984.7 2 146.0528 3244.7 3 146.06 823.4 1 147.048 2032.8 2 147.0605 4588.9 5 148.0557 5886.2 7 149.0512 2787 3 151.0431 871.1 1 154.0652 12229 14 155.0603 6542.2 7 155.0731 3354.5 4 156.0683 1830.5 2 156.0813 1496 1 158.0602 900.5 1 159.0482 2187 2 160.0434 3015.6 3 160.0557 5741.8 7 161.0511 2568.6 3 161.0635 4280.8 5 162.0352 2493 3 162.0588 5075.6 6 162.0716 2882.6 3 163.0668 1980.8 2 164.0506 4795.6 5 166.0658 1789.3 2 167.0607 4014.1 4 167.0731 1683.5 2 168.0683 7424.6 9 168.0808 937.9 1 169.0523 869.3 1 169.0761 5034.8 6 172.0558 21150.4 25 173.0512 2894.4 3 173.0637 11247 13 174.0351 1736.5 2 174.0594 4194.5 5 174.0714 13757.1 16 175.0669 6558.9 8 176.0508 1716.7 2 176.0745 2963.7 3 178.0428 1610 1 178.0539 11402.5 13 178.0661 8224.7 10 179.0381 1955 2 179.061 4522.4 5 180.0809 935.3 1 181.076 3604.3 4 182.0605 2383.4 2 182.084 2243.7 2 183.0916 3224.5 3 184.0394 2296.8 2 184.0563 943.5 1 184.0629 3499.8 4 185.0639 5034.7 6 185.071 1295.9 1 186.059 7651.9 9 186.0714 5792 7 187.0302 3985.1 4 187.0433 4004.8 4 187.0668 38820.7 47 188.0145 2146.1 2 188.0508 3383.6 4 188.0747 4730.8 5 188.0874 2786.9 3 189.046 8141.2 9 189.0823 6288.4 7 189.0951 2550 3 190.0539 5864 7 191.0617 5112.2 6 192.0691 2233.5 2 192.0809 2877.1 3 193.0762 5951.8 7 193.089 989 1 194.0838 2351.9 2 195.0328 903.1 1 195.0553 3081.2 3 195.0918 1821.1 2 196.0634 6618.6 8 197.0477 2005.6 2 197.0708 3474.5 4 197.1075 6369.7 7 198.0716 2670.8 3 199.0668 13001.5 15 200.0507 6288.9 7 200.0745 7080.3 8 201.0585 15903.9 19 201.0823 6069.4 7 202.0303 1968.3 2 202.054 2568.6 3 202.0664 37362.1 45 202.09 4693.2 5 203.0616 31404.4 38 203.098 3311.5 4 205.0538 3592 4 205.0772 2870.8 3 206.0844 1706.7 2 207.0922 2923.7 3 209.0712 2594.7 3 209.1075 931.3 1 211.0662 3544.1 4 211.0876 1068.5 1 212.0748 5154.4 6 212.0873 12261.7 14 213.0457 885 1 213.0826 11830.2 14 213.0947 3102.7 3 214.0666 3147.8 3 214.0904 13091.5 15 215.0253 35647.9 43 215.0618 50325.1 61 215.0976 4704.5 5 216.0697 9143.8 11 216.0823 1819.4 2 217.0409 10572.7 12 217.0774 9322.4 11 218.0488 23567 28 219.0924 5240.4 6 220.0408 1637.3 1 221.0484 1049.1 1 221.0713 3718.8 4 221.1077 2533.9 3 222.0435 1982.6 2 222.0798 831.5 1 223.0504 927.4 1 223.0865 991.4 1 224.0748 2064.9 2 225.0824 2681.8 3 226.0535 2373.2 2 226.0904 2861.4 3 227.0617 12246.6 14 227.098 4906.8 5 228.0539 1799.9 2 228.0695 2867.2 3 228.0822 1856.3 2 229.0411 1059.9 1 229.0773 16506.7 20 230.0485 2174 2 230.0853 3690.1 4 231.0563 2077.5 2 231.0931 13224 16 233.036 15608.6 19 233.048 2513.9 3 234.0565 2104.5 2 235.0514 6352.1 7 235.0641 2561.7 3 235.087 2446.6 2 236.0592 9716.6 11 237.1022 10328.1 12 238.098 5722.5 6 239.0615 1701.9 2 239.0979 11121.2 13 240.07 1049.3 1 240.0815 850.1 1 240.1059 3622.7 4 241.0772 13963.2 17 241.1141 1043.4 1 242.0855 3367.2 4 243.0564 5002.1 6 243.0928 3613.4 4 245.0726 1785.2 2 245.1089 2117.1 2 246.0566 974.9 1 247.052 2813.6 3 248.1185 989 1 252.1131 3478.4 4 253.0774 2776.2 3 254.0483 7915.1 9 255.0566 246739 301 256.0644 13540 16 257.0724 2220.8 2 257.1087 1929.7 2 261.0674 2236.8 2 263.0832 863.8 1 264.0769 2906.7 3 267.0925 4537.2 5 268.1001 1617 1 269.0722 1754.6 2 269.1081 915.7 1 271.1243 6903.1 8 273.0672 68332.3 83 274.0751 3661 4 275.0828 5938.1 7 277.0989 3541.9 4 278.0924 2182.3 2 279.1007 2827.6 3 281.1091 1908.2 2 282.0883 912.1 1 283.1244 1966.3 2 284.0827 2283 2 287.0832 3130.9 3 289.0983 3106.6 3 298.0986 3527.9 4 301.0985 2774.3 3 315.1143 1804 2 340.1465 2106.4 2 358.1564 30660 37 //