MassBank Record: EQ326404



 Dexamethasone acetate; LC-ESI-QFT; MS2; CE: 60; R=35000; [M+H]+ 
Mass Spectrum
Chemical Structure
Generated by the Chemistry Development Kit (http://github.com/cdk) \n

ACCESSION: EQ326404
RECORD_TITLE: Dexamethasone acetate; LC-ESI-QFT; MS2; CE: 60; R=35000; [M+H]+
DATE: 2015.08.25
AUTHORS: Beck BDepartment of Environmental Chemistry, Eawag, Stravs MDepartment of Environmental Chemistry, Eawag, Schymanski EDepartment of Environmental Chemistry, Eawag, Singer HDepartment of Environmental Chemistry, Eawag, Department of Environmental Chemistry, Eawag
LICENSE: CC BY
COPYRIGHT: Copyright (C) 2015 Eawag, Duebendorf, Switzerland
COMMENT: CONFIDENCE standard compound
COMMENT: EAWAG_UCHEM_ID 3264

CH$NAME: Dexamethasone acetate CH$NAME: Dexamethason-21-acetate CH$NAME: [2-(9-fluoro-11,17-dihydroxy-10,13,16-trimethyl-3-oxo-6,7,8,11,12,14,15,16-octahydrocyclopenta[a]phenanthren-17-yl)-2-oxoethyl] acetate CH$COMPOUND_CLASS: N/A; Environmental Standard CH$FORMULA: C24H31FO6 CH$EXACT_MASS: 434.21047 CH$SMILES: CC1CC2C3CCC4=CC(=O)C=CC4(C3(C(CC2(C1(C(=O)COC(=O)C)O)C)O)F)C CH$IUPAC: InChI=1S/C24H31FO6/c1-13-9-18-17-6-5-15-10-16(27)7-8-21(15,3)23(17,25)19(28)11-22(18,4)24(13,30)20(29)12-31-14(2)26/h7-8,10,13,17-19,28,30H,5-6,9,11-12H2,1-4H3 CH$LINK: CAS 1177-87-3 CH$LINK: PUBCHEM 3680 CH$LINK: INCHIKEY AKUJBENLRBOFTD-UHFFFAOYSA-N CH$LINK: CHEMSPIDER 3552
AC$INSTRUMENT: Q Exactive Plus Orbitrap Thermo Scientific AC$INSTRUMENT_TYPE: LC-ESI-QFT AC$MASS_SPECTROMETRY: MS_TYPE MS2 AC$MASS_SPECTROMETRY: ION_MODE POSITIVE AC$MASS_SPECTROMETRY: IONIZATION ESI AC$MASS_SPECTROMETRY: FRAGMENTATION_MODE HCD AC$MASS_SPECTROMETRY: COLLISION_ENERGY 60 (nominal) AC$MASS_SPECTROMETRY: RESOLUTION 35000 AC$CHROMATOGRAPHY: COLUMN_NAME XBridge C18 3.5um, 2.1x50mm, Waters AC$CHROMATOGRAPHY: FLOW_GRADIENT 90/10 at 0 min, 50/50 at 4 min, 5/95 at 17 min, 5/95 at 25 min, 90/10 at 25.1 min, 90/10 at 30 min AC$CHROMATOGRAPHY: FLOW_RATE 200 ul/min AC$CHROMATOGRAPHY: RETENTION_TIME 10.2 min AC$CHROMATOGRAPHY: SOLVENT A water with 0.1% formic acid AC$CHROMATOGRAPHY: SOLVENT B methanol with 0.1% formic acid
MS$FOCUSED_ION: BASE_PEAK 435.2176 MS$FOCUSED_ION: PRECURSOR_M/Z 435.2177 MS$FOCUSED_ION: PRECURSOR_TYPE [M+H]+ MS$DATA_PROCESSING: RECALIBRATE loess on assigned fragments and MS1 MS$DATA_PROCESSING: REANALYZE Peaks with additional N2/O included MS$DATA_PROCESSING: WHOLE RMassBank 1.9.6
PK$SPLASH: splash10-05fs-1950000000-500ebdc7f18c4076ed49 PK$ANNOTATION: m/z tentative_formula formula_count mass error(ppm) 50.015 C4H2+ 1 50.0151 -1.43 53.0022 C3HO+ 1 53.0022 0.92 53.0386 C4H5+ 1 53.0386 -0.12 55.0179 C3H3O+ 1 55.0178 0.34 55.0543 C4H7+ 1 55.0542 0.61 57.0335 C3H5O+ 1 57.0335 0.33 57.0699 C4H9+ 1 57.0699 0.06 59.0491 C3H7O+ 1 59.0491 -0.02 61.0284 C2H5O2+ 1 61.0284 0.72 65.0386 C5H5+ 1 65.0386 -0.25 67.0542 C5H7+ 1 67.0542 0.35 69.0335 C4H5O+ 1 69.0335 0.27 69.0699 C5H9+ 1 69.0699 -0.1 71.0128 C3H3O2+ 1 71.0128 0.76 71.0491 C4H7O+ 1 71.0491 -0.16 75.044 C3H7O2+ 1 75.0441 -0.48 77.0384 C6H5+ 1 77.0386 -2.03 79.0542 C6H7+ 1 79.0542 -0.08 81.0699 C6H9+ 1 81.0699 0.29 83.0491 C5H7O+ 1 83.0491 -0.02 83.0856 C6H11+ 1 83.0855 1 85.0648 C5H9O+ 1 85.0648 -0.13 91.0543 C7H7+ 1 91.0542 0.59 93.07 C7H9+ 1 93.0699 0.79 95.0492 C6H7O+ 1 95.0491 0.83 95.0856 C7H11+ 1 95.0855 0.35 97.0648 C6H9O+ 1 97.0648 0.09 99.044 C5H7O2+ 1 99.0441 -0.06 101.0235 C4H5O3+ 1 101.0233 1.98 101.0598 C5H9O2+ 1 101.0597 0.93 103.0543 C8H7+ 1 103.0542 1.1 104.0623 C8H8+ 1 104.0621 2.39 105.0449 C6H5N2+ 1 105.0447 1.29 105.07 C8H9+ 1 105.0699 0.7 107.0491 C7H7O+ 1 107.0491 0.08 107.0856 C8H11+ 1 107.0855 0.5 108.057 C7H8O+ 1 108.057 0.31 109.0649 C7H9O+ 1 109.0648 0.81 109.1012 C8H13+ 1 109.1012 0.49 111.0441 C6H7O2+ 1 111.0441 0.58 111.0805 C7H11O+ 1 111.0804 0.8 113.0598 C6H9O2+ 1 113.0597 1.27 115.0542 C9H7+ 1 115.0542 0.12 115.0754 C6H11O2+ 1 115.0754 0.12 116.062 C9H8+ 1 116.0621 -0.45 117.0547 C5H9O3+ 1 117.0546 1.02 117.0699 C9H9+ 1 117.0699 0.46 119.0605 C7H7N2+ 1 119.0604 0.8 119.0856 C9H11+ 1 119.0855 0.78 121.0649 C8H9O+ 1 121.0648 0.65 121.1012 C9H13+ 1 121.1012 0.36 123.0805 C8H11O+ 1 123.0804 0.31 123.1168 C9H15+ 1 123.1168 -0.54 125.0399 C7H6FO+ 1 125.0397 1.28 125.0599 C7H9O2+ 1 125.0597 1.63 125.0961 C8H13O+ 1 125.0961 -0.33 128.0621 C10H8+ 1 128.0621 0.14 129.0699 C10H9+ 1 129.0699 0.1 130.0778 C10H10+ 1 130.0777 0.68 131.049 C9H7O+ 1 131.0491 -0.77 131.0856 C10H11+ 1 131.0855 0.71 132.057 C9H8O+ 1 132.057 0.48 133.0649 C9H9O+ 1 133.0648 0.67 133.1013 C10H13+ 1 133.1012 0.78 134.0726 C9H10O+ 1 134.0726 -0.05 135.0805 C9H11O+ 1 135.0804 0.29 137.06 C8H9O2+ 1 137.0597 2.15 137.0963 C9H13O+ 1 137.0961 1.45 139.0753 C8H11O2+ 1 139.0754 -0.33 141.07 C11H9+ 1 141.0699 0.73 142.0779 C11H10+ 1 142.0777 1.33 143.0856 C11H11+ 1 143.0855 0.79 144.0572 C10H8O+ 1 144.057 1.28 144.0936 C11H12+ 1 144.0934 1.86 145.0649 C10H9O+ 1 145.0648 0.68 145.1012 C11H13+ 1 145.1012 0.5 146.0726 C10H10O+ 1 146.0726 0.09 147.0805 C10H11O+ 1 147.0804 0.4 149.0962 C10H13O+ 1 149.0961 0.86 151.0754 C9H11O2+ 1 151.0754 0.56 152.0621 C12H8+ 1 152.0621 0.38 153.07 C12H9+ 1 153.0699 1.07 153.0912 C9H13O2+ 1 153.091 1.4 154.0777 C12H10+ 1 154.0777 -0.21 155.0605 C10H7N2+ 1 155.0604 0.68 155.0855 C12H11+ 1 155.0855 0.02 156.0571 C11H8O+ 1 156.057 0.54 156.0934 C12H12+ 1 156.0934 0.18 157.0648 C11H9O+ 1 157.0648 -0.26 157.1013 C12H13+ 1 157.1012 0.97 158.0727 C11H10O+ 1 158.0726 0.53 159.0805 C11H11O+ 1 159.0804 0.56 160.0884 C11H12O+ 1 160.0883 0.58 161.0599 C10H9O2+ 1 161.0597 1.14 161.0962 C11H13O+ 1 161.0961 0.43 163.0752 C10H11O2+ 1 163.0754 -0.77 163.1118 C11H15O+ 1 163.1117 0.6 165.07 C13H9+ 1 165.0699 0.5 165.0913 C10H13O2+ 1 165.091 1.6 166.0777 C13H10+ 1 166.0777 -0.01 167.0705 C9H11O3+ 1 167.0703 1.25 167.0856 C13H11+ 1 167.0855 0.56 167.1066 C10H15O2+ 1 167.1067 -0.28 168.057 C12H8O+ 1 168.057 0.26 168.0936 C13H12+ 1 168.0934 1.54 169.0649 C12H9O+ 1 169.0648 0.82 169.0764 C11H9N2+ 2 169.076 2.04 169.1011 C13H13+ 1 169.1012 -0.16 170.0726 C12H10O+ 1 170.0726 -0.15 170.109 C13H14+ 1 170.109 -0.01 171.0805 C12H11O+ 1 171.0804 0.4 172.0884 C12H12O+ 1 172.0883 0.54 173.0962 C12H13O+ 1 173.0961 0.63 175.0755 C11H11O2+ 1 175.0754 0.94 175.1118 C12H15O+ 1 175.1117 0.45 177.0704 C14H9+ 2 177.0699 3.07 177.0913 C11H13O2+ 1 177.091 1.38 178.0777 C14H10+ 1 178.0777 0.1 179.0856 C14H11+ 1 179.0855 0.46 180.0934 C14H12+ 1 180.0934 0.32 181.0648 C13H9O+ 1 181.0648 -0.12 181.1012 C14H13+ 1 181.1012 0.35 182.0727 C13H10O+ 1 182.0726 0.57 182.1093 C14H14+ 2 182.109 1.47 183.0805 C13H11O+ 1 183.0804 0.54 183.117 C14H15+ 1 183.1168 1.05 184.0884 C13H12O+ 1 184.0883 0.73 185.0962 C13H13O+ 1 185.0961 0.37 186.104 C13H14O+ 1 186.1039 0.4 187.0753 C12H11O2+ 1 187.0754 -0.03 187.1117 C13H15O+ 1 187.1117 -0.12 189.0701 C15H9+ 1 189.0699 0.97 189.0912 C12H13O2+ 2 189.091 1.24 190.0777 C15H10+ 1 190.0777 0.04 191.0856 C15H11+ 1 191.0855 0.59 192.0934 C15H12+ 1 192.0934 0.25 193.1013 C15H13+ 1 193.1012 0.79 194.0727 C14H10O+ 1 194.0726 0.38 194.1091 C15H14+ 1 194.109 0.51 195.0806 C14H11O+ 1 195.0804 0.66 195.1169 C15H15+ 1 195.1168 0.37 196.0884 C14H12O+ 2 196.0883 0.83 197.0962 C14H13O+ 1 197.0961 0.6 197.1325 C15H17+ 1 197.1325 0.27 198.0677 C13H10O2+ 2 198.0675 0.95 198.1041 C14H14O+ 1 198.1039 0.72 199.0754 C13H11O2+ 1 199.0754 0.17 199.1118 C14H15O+ 1 199.1117 0.34 201.0911 C13H13O2+ 1 201.091 0.57 202.0779 C16H10+ 2 202.0777 0.73 203.0855 C16H11+ 1 203.0855 0.07 204.0935 C16H12+ 2 204.0934 0.92 205.0649 C15H9O+ 2 205.0648 0.58 205.1011 C16H13+ 1 205.1012 -0.28 206.0727 C15H10O+ 1 206.0726 0.21 206.1093 C16H14+ 2 206.109 1.4 207.0807 C15H11O+ 2 207.0804 1.06 207.117 C16H15+ 2 207.1168 0.64 208.0884 C15H12O+ 2 208.0883 0.79 209.0963 C15H13O+ 2 209.0961 0.81 209.1326 C16H17+ 1 209.1325 0.35 210.104 C15H14O+ 2 210.1039 0.54 211.0753 C14H11O2+ 1 211.0754 -0.5 211.1119 C15H15O+ 2 211.1117 0.7 212.1197 C15H16O+ 2 212.1196 0.77 213.091 C14H13O2+ 1 213.091 -0.22 213.1275 C15H17O+ 2 213.1274 0.46 215.0856 C17H11+ 2 215.0855 0.34 215.1069 C14H15O2+ 2 215.1067 1.09 216.0933 C17H12+ 1 216.0934 -0.47 217.1013 C17H13+ 2 217.1012 0.66 218.073 C16H10O+ 2 218.0726 1.76 218.1092 C17H14+ 2 218.109 0.91 219.0809 C16H11O+ 2 219.0804 2 219.1169 C17H15+ 2 219.1168 0.52 220.0885 C16H12O+ 2 220.0883 0.92 220.1249 C17H16+ 2 220.1247 1.22 221.0962 C16H13O+ 2 221.0961 0.63 221.1325 C17H17+ 2 221.1325 0.19 222.1041 C16H14O+ 2 222.1039 0.65 223.1119 C16H15O+ 2 223.1117 0.49 224.0833 C15H12O2+ 2 224.0832 0.49 224.1198 C16H16O+ 2 224.1196 1.09 225.0909 C15H13O2+ 1 225.091 -0.38 225.1276 C16H17O+ 2 225.1274 0.79 226.0769 C18H10+ 1 226.0777 -3.77 226.0988 C15H14O2+ 1 226.0988 0.04 226.1354 C16H18O+ 2 226.1352 0.86 227.0858 C18H11+ 2 227.0855 1.25 227.1067 C15H15O2+ 2 227.1067 0.06 227.1431 C16H19O+ 2 227.143 0.43 228.0932 C18H12+ 1 228.0934 -0.88 229.1013 C18H13+ 2 229.1012 0.54 230.1091 C18H14+ 2 230.109 0.47 231.0805 C17H11O+ 2 231.0804 0.34 231.1169 C18H15+ 2 231.1168 0.49 232.0884 C17H12O+ 2 232.0883 0.49 233.0961 C17H13O+ 2 233.0961 0.25 233.133 C18H17+ 2 233.1325 2.11 234.104 C17H14O+ 2 234.1039 0.36 234.1407 C18H18+ 2 234.1403 1.53 235.1119 C17H15O+ 2 235.1117 0.5 235.1477 C18H19+ 1 235.1481 -1.65 236.1197 C17H16O+ 2 236.1196 0.65 237.1275 C17H17O+ 2 237.1274 0.5 238.099 C16H14O2+ 2 238.0988 0.58 238.1354 C17H18O+ 2 238.1352 0.85 239.1432 C17H19O+ 2 239.143 0.87 240.1144 C16H16O2+ 1 240.1145 -0.55 241.1015 C19H13+ 2 241.1012 1.51 241.1224 C16H17O2+ 2 241.1223 0.43 242.1092 C19H14+ 2 242.109 0.94 243.1168 C19H15+ 2 243.1168 0.01 244.0888 C18H12O+ 2 244.0883 2.15 244.1247 C19H16+ 2 244.1247 0.36 245.0962 C18H13O+ 2 245.0961 0.44 245.1329 C19H17+ 2 245.1325 1.93 246.104 C18H14O+ 2 246.1039 0.18 246.1401 C19H18+ 1 246.1403 -0.98 247.1118 C18H15O+ 2 247.1117 0.36 247.1479 C19H19+ 1 247.1481 -0.92 248.1197 C18H16O+ 2 248.1196 0.58 249.091 C17H13O2+ 2 249.091 0.02 249.1275 C18H17O+ 2 249.1274 0.6 250.1354 C18H18O+ 2 250.1352 0.89 251.1066 C17H15O2+ 2 251.1067 -0.14 251.1435 C18H19O+ 2 251.143 1.71 252.1512 C18H20O+ 2 252.1509 1.28 253.1015 C20H13+ 2 253.1012 1.43 253.1222 C17H17O2+ 2 253.1223 -0.26 253.1591 C18H21O+ 2 253.1587 1.42 256.1241 C20H16+ 1 256.1247 -1.96 257.096 C19H13O+ 2 257.0961 -0.43 257.132 C20H17+ 1 257.1325 -1.89 258.1044 C19H14O+ 2 258.1039 1.91 258.1407 C20H18+ 2 258.1403 1.39 259.1118 C19H15O+ 2 259.1117 0.07 259.1482 C20H19+ 2 259.1481 0.17 260.1196 C19H16O+ 2 260.1196 0.05 261.1275 C19H17O+ 2 261.1274 0.22 262.1353 C19H18O+ 2 262.1352 0.43 263.1063 C18H15O2+ 1 263.1067 -1.2 263.1432 C19H19O+ 2 263.143 0.6 264.1509 C19H20O+ 2 264.1509 0.13 265.1224 C18H17O2+ 2 265.1223 0.24 265.159 C19H21O+ 2 265.1587 1.24 267.138 C18H19O2+ 2 267.138 0.01 267.1743 C19H23O+ 2 267.1743 -0.01 268.1249 C21H16+ 2 268.1247 0.81 270.1042 C20H14O+ 2 270.1039 0.9 271.1116 C20H15O+ 2 271.1117 -0.52 272.1191 C20H16O+ 1 272.1196 -1.79 273.1275 C20H17O+ 2 273.1274 0.32 274.0991 C19H14O2+ 2 274.0988 0.98 274.1349 C20H18O+ 1 274.1352 -1.19 275.1071 C19H15O2+ 2 275.1067 1.61 275.1432 C20H19O+ 2 275.143 0.68 276.151 C20H20O+ 2 276.1509 0.63 277.1222 C16H18FO3+ 2 277.1234 -4.36 277.1588 C20H21O+ 2 277.1587 0.5 278.1665 C20H22O+ 2 278.1665 0.12 279.1381 C19H19O2+ 2 279.138 0.66 279.1744 C20H23O+ 2 279.1743 0.28 283.1487 C19H20FO+ 2 283.1493 -1.87 285.1271 C21H17O+ 1 285.1274 -1.02 286.1354 C21H18O+ 2 286.1352 0.54 287.143 C21H19O+ 2 287.143 -0.01 289.1223 C20H17O2+ 2 289.1223 0.05 289.1587 C21H21O+ 2 289.1587 -0.11 290.1295 C20H18O2+ 1 290.1301 -2.11 291.1748 C21H23O+ 2 291.1743 1.71 301.1587 C22H21O+ 2 301.1587 0.19 304.1459 C21H20O2+ 2 304.1458 0.39 319.1691 C22H23O2+ 2 319.1693 -0.62 PK$NUM_PEAK: 276 PK$PEAK: m/z int. rel.int. 50.015 24316.3 2 53.0022 45258.6 4 53.0386 219378.9 19 55.0179 316352.7 28 55.0543 581601.7 51 57.0335 246155.2 21 57.0699 129125 11 59.0491 55185.7 4 61.0284 552778.1 48 65.0386 197542 17 67.0542 1225201.6 108 69.0335 1049233.1 92 69.0699 848139.1 75 71.0128 91504.5 8 71.0491 283989.7 25 75.044 44603.7 3 77.0384 229641.2 20 79.0542 1382741.8 122 81.0699 1142079 101 83.0491 252768.8 22 83.0856 112683.7 9 85.0648 143919.2 12 91.0543 3170431.2 280 93.07 2582876.5 228 95.0492 1006955.3 89 95.0856 1263800.8 111 97.0648 528697.4 46 99.044 96731.1 8 101.0235 279517.3 24 101.0598 116103.9 10 103.0543 235446 20 104.0623 29768.6 2 105.0449 192121.6 17 105.07 3826756.5 338 107.0491 433888.8 38 107.0856 3498509.8 309 108.057 61255.1 5 109.0649 746363.9 66 109.1012 632905.9 56 111.0441 35495.7 3 111.0805 265414.7 23 113.0598 56514 5 115.0542 702806.1 62 115.0754 62642.1 5 116.062 210681.1 18 117.0547 238476.2 21 117.0699 1138436.2 100 119.0605 223459.1 19 119.0856 4223720.5 373 121.0649 6940845.5 614 121.1012 1017110.2 90 123.0805 912657.9 80 123.1168 99109 8 125.0399 31266.6 2 125.0599 339859.4 30 125.0961 194454.5 17 128.0621 1501028.4 132 129.0699 1033315.2 91 130.0778 217448.4 19 131.049 150477.5 13 131.0856 2264646.8 200 132.057 582487.2 51 133.0649 808599.6 71 133.1013 1028396.7 91 134.0726 39443.8 3 135.0805 2599739.5 230 137.06 136190.2 12 137.0963 191809.8 16 139.0753 59419.4 5 141.07 927870.1 82 142.0779 545620.7 48 143.0856 2533793.2 224 144.0572 441164.8 39 144.0936 30282.4 2 145.0649 2545547.2 225 145.1012 1112019.4 98 146.0726 397862.5 35 147.0805 11286085 999 149.0962 990604.5 87 151.0754 290805.5 25 152.0621 139064.7 12 153.07 250097.8 22 153.0912 212718.3 18 154.0777 230877.5 20 155.0605 154067.4 13 155.0855 1097996.4 97 156.0571 125992 11 156.0934 225312 19 157.0648 303626.6 26 157.1013 695408.2 61 158.0727 1635672.4 144 159.0805 4450483 393 160.0884 154186.4 13 161.0599 329727.8 29 161.0962 1671771.9 147 163.0752 273297.6 24 163.1118 45117.1 3 165.07 626398 55 165.0913 114851.8 10 166.0777 278990.8 24 167.0705 105521.7 9 167.0856 871806.1 77 167.1066 151267.8 13 168.057 265279.2 23 168.0936 244591.8 21 169.0649 581990.4 51 169.0764 165131.2 14 169.1011 615193.9 54 170.0726 364339.1 32 170.109 56065.6 4 171.0805 6013678.5 532 172.0884 563515.3 49 173.0962 2754075.5 243 175.0755 63992.9 5 175.1118 135104.4 11 177.0704 27646.5 2 177.0913 110267.5 9 178.0777 698562.6 61 179.0856 1816302.6 160 180.0934 487257.6 43 181.0648 495197.6 43 181.1012 733246.6 64 182.0727 704679.6 62 182.1093 161888 14 183.0805 1152405.4 102 183.117 429129.4 37 184.0884 343967.7 30 185.0962 2896829.5 256 186.104 107035.2 9 187.0753 835808.9 73 187.1117 521396.1 46 189.0701 537491.1 47 189.0912 110011.9 9 190.0777 433093.8 38 191.0856 630449.8 55 192.0934 1023168.9 90 193.1013 1421193.6 125 194.0727 313490.1 27 194.1091 1062597.1 94 195.0806 1313587.2 116 195.1169 604989.1 53 196.0884 1517010.1 134 197.0962 2286963.8 202 197.1325 193289 17 198.0677 43635.7 3 198.1041 471849.9 41 199.0754 115793.5 10 199.1118 648321.6 57 201.0911 132379.3 11 202.0779 329505 29 203.0855 689017.8 60 204.0935 1820126.6 161 205.0649 178353.8 15 205.1011 693773.9 61 206.0727 146406.3 12 206.1093 556645.6 49 207.0807 654683.9 57 207.117 866323.5 76 208.0884 1828783.2 161 209.0963 2457027 217 209.1326 524159.3 46 210.104 1340463 118 211.0753 168118.2 14 211.1119 1839515.4 162 212.1197 928751.8 82 213.091 140331 12 213.1275 654856.7 57 215.0856 306331.6 27 215.1069 133484.5 11 216.0933 342574.4 30 217.1013 388388.2 34 218.073 50716.8 4 218.1092 186342.1 16 219.0809 448655.3 39 219.1169 960861.7 85 220.0885 718186.8 63 220.1249 178184.9 15 221.0962 2078166.6 183 221.1325 311675 27 222.1041 5195401 459 223.1119 1841283.1 162 224.0833 104131.3 9 224.1198 608826.2 53 225.0909 168425.4 14 225.1276 984104.5 87 226.0769 29338.5 2 226.0988 213440.3 18 226.1354 132192.6 11 227.0858 110994.8 9 227.1067 116751.5 10 227.1431 902827.2 79 228.0932 107049.3 9 229.1013 556660.4 49 230.1091 398290.8 35 231.0805 221028.8 19 231.1169 404407.7 35 232.0884 274767.7 24 233.0961 918678.1 81 233.133 243205.7 21 234.104 875748.2 77 234.1407 135190.2 11 235.1119 3269020.5 289 235.1477 214352.7 18 236.1197 628016.4 55 237.1275 2134768.5 188 238.099 305528.1 27 238.1354 278017.3 24 239.1073 181511.7344 16 239.1432 422110.7 37 240.1144 58706 5 241.1015 57617.6 5 241.1224 99803.6 8 242.1092 201610.5 17 243.1168 583600.6 51 244.0888 130242.6 11 244.1247 251173.3 22 245.0962 679593.3 60 245.1329 222105.8 19 246.104 696416.6 61 246.1401 121065.2 10 247.1118 1499712.6 132 247.1479 102760.7 9 248.1197 1367122.4 121 249.091 63242.9 5 249.1275 1019731.1 90 250.1354 136230.8 12 251.1066 57142.6 5 251.1435 333481.6 29 252.1512 128915.4 11 253.1015 188796.3 16 253.1222 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